Redox induced radical and radical ionic carbon-carbon bond forming reactions

No abstract is available for this paper.

• Publication year

  1995

• Venue

  Tetrahedron

• Publication date

  1995-07-10

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1016/0040-4020(95)00434-A
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• New Mechanistic Insights into Reductions of Halides and Radicals with Samarium(II) Iodide

  2010cited by this paper
• Single Electron Transfer and Nucleophilic Substitution

  2010cited by this paper
• ELECTRON-TRANSFER PROCESSES: PEROXYDISULFATE, A USEFUL AND VERSATILE REAGENT IN ORGANIC CHEMISTRY

  2002cited by this paper
• Electron Transfer and Radical Processes in Transition-Metal Chemistry

  1995cited by this paper
• Rearrangements in the cerium(IV) and manganese(III) oxidations of substituted naphthalenes and the NIH shift mechanism

  1994cited by this paper
• Transition Metal-Promoted Free-Radical Reactions in Organic Synthesis: The Formation of Carbon-Carbon Bonds

  1994cited by this paper
• Manganese(III) acetate initiated oxidative free radical reaction between N-aroylindoles and dimethyl malonate

  1994cited by this paper
• Transition metal-catalyzed chlorine transfer cyclizations of carbon-centered glycine radicals; A novel synthetic route to cyclic α-amino acids

  1994cited by this paper
• A convenient stereoselective synthesis of fluorinated α-alkylidene-γ-butyrolactone derivatives

  1994cited by this paper
• Transition metal-catalysed chlorine transfer radical cyclizations of 2-(3-alken-1-oxy)-2-chloroacetates; formal total synthesis of avenaciolide and isoavenaciolide

  1994cited by this paper
• Cobalt cluster-directed, manganese(III)-mediated chemo- and stereoselective radical reactions of 1-alken-3-ynes

  1994cited by this paper
• MECHANISTIC EVALUATION OF DISSOCIATIVE ELECTRON-TRANSFER AND NUCLEOPHILIC SUBSTITUTION REACTIONS

  1994cited by this paper
• A novel and efficient synthesis of cyclic and acyclic 1,5-alkadiynes by selective coupling of Co2(CO)6-complexed propargyl radicals

  1994cited by this paper
• Radical Ion Probes. 3. The Importance of Resonance vs. Strain Energy in the Design of SET Probes Based upon the Cyclopropylcarbinyl-to-Homoallyl Radical Rearrangement

  1994cited by this paper
• EPR characterization of radical cations generated by one-electron oxidation of N-methyl-p-anisidine

  1994cited by this paper
• Preparation and Reactions of Polyfunctional Organozinc Reagents in Organic Synthesis

  1994cited by this paper
• A short, flexible approach to vitamin D3 analogues with modified side chains

  1994cited by this paper
• New perspectives in the formation of the Grignard reagent

  1994cited by this paper
• Mechanistic studies on zinc-induced addition of CF2Br2 to olefins. A novel radical reductive cyclopropanation on the zinc surface

  1994cited by this paper
• Total synthesis of taxol

  1994cited by this paper
• Total synthesis of upial, a marine sesquiterpene possessing bicyclo[3.3.1]nonane ring system

  1994cited by this paper
• Studies on sulfinatodehalogenation. Part 30. Synthesis of 3-perfluoroalkylated coumarins, thiocoumarins and 2-quinolones by direct perfluoroalkylation with perfluoroalkyl iodides and sodium hydroxymethanesulfinate

  1994cited by this paper
• Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis

  1994cited by this paper
• Solvent effect on the ET/SN2 competition in the reaction of a radical anion with some benzyl bromides

  1994cited by this paper
• Lewis Acid-Promoted Diastereoselective Radical Cyclization Using Chiral .alpha.,.beta.-Unsaturated Esters

  1994cited by this paper
• Ruthenium dioxide in fluoro acid medium V. Application to the non phenolic oxidative coupling of diarylbutanes. Conformational studies of cis and trans deoxyschizandrins.

  1994cited by this paper
• Convenient preparation of (R)- and (S)-1-(2-amino-3-iodo)propanol derivatives from (S)-serine: Application in radical addition reactions

  1994cited by this paper
• Cation radical-induced Claisen rearrangement of aryl allenylmethyl ethers

  1994cited by this paper
• Mechanism of the Gif-Barton type alkane functionalization by halide and pseudohalide ions

  1994cited by this paper
• EARLY TRANSITION METAL ALKOXIDE COMPLEXES BEARING HOMOCHIRAL TRIALKANOLAMINE LIGANDS

  1994cited by this paper
• Cobalt(II)-Catalyzed Reaction of Enolizable Aldehydes with Alkenes in the Presence of Dioxygen: The Role of Acyl Radical

  1994cited by this paper
• Zinc Chloride as a Radical Initiator as Well as a Chelating Agent

  1994cited by this paper
• Single electron transfer in nucleophilic aliphatic substitution. Evidence for single electron transfer in the reactions of 1-halonorbornanes with various nucleophiles

  1994cited by this paper
• SRN1 reactions of chlorotrifluoromethyl pyridines with naphtholate, phenolate and malonate anions

  1993cited by this paper
• ELECTRON STORAGE AND TRANSFER IN ORGANIC REDOX SYSTEMS WITH MULTIPLE ELECTROPHORES

  1993cited by this paper
• Addition of diethyl bromodifluoromethylphosphonate to various alkenes initiated by Co(III)/Zn bimetal redox system

  1993cited by this paper
• Oxovanadium-induced oxidative desilylation of allylic and benzylic silanes

  1993cited by this paper
• Synthesis of fused acetal derivatives by manganic acetate promoted additions to endocyclic enol ethers

  1993cited by this paper
• Electron transfer, bond breaking, and bond formation

  1993cited by this paper
• Use of fragmentation probes in a study of the reduction reactions of 8-B-4 complexes

  1993cited by this paper
• Single Electron Transfer in Michael Induced Ring Closure reactions

  1993cited by this paper
• γ-selectivity in the ceric ammonium nitrate promoted oxidative addition of silyl dienol ethers to silyl enol ethers

  1993cited by this paper
• Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)

  1993cited by this paper
• Studies on macrocyclic diterpenoids. Part 10. First total synthesis of (±)-isosarcophytol-A

  1993cited by this paper
• Isotopic exchange involving the [8]annulene anion radical and its dimerization to the [16]annulene anion radical

  1993cited by this paper
• New methods for reductive free-radical cyclizations of α-bromoacetals to 2-alkoxytetrahydrofurans with activated chromium(II)-acetate

  1993cited by this paper
• Divalent Lanthanide Derivatives in Organic Synthesis: New Developments in SmI2-Mediated Barbier Type Reactions.

  1993cited by this paper
• Chemistry of and with Highly Reactive Metals

  1993cited by this paper
• Oxidative coupling of arylglycine-containing peptides. A biomimetic approach to the synthesis of the macrocyclic actinoidinic-containing vancomycin subunit

  1993cited by this paper
• Low-valent titanium induced reductive coupling reaction of carboxylic derivatives with aromatic ketones

  1993cited by this paper
• Total synthesis of upial

  1993cited by this paper
• Synthesis of oxaspirolactones by manganic acetate promoted additions to exocyclic enol lactones

  1993cited by this paper
• Generation of radical cations from enamines and their addition to unactivated olefins

  1993cited by this paper
• Mechanistic studies on the nickel-catalyzed polymerization of isocyanides

  1993cited by this paper
• Oxidation of ketones by ferric perchlorate in the presence of conjugated dienes to hexahydrofuro[2,3-b]furans and 1,6-dioxaspiro[4,4]nonanes

  1993cited by this paper
• Oxidative free-radical cyclization of allylic α-chloromalonates. Synthesis of (±)-avenaciolide.

  1993cited by this paper
• Manganese-(II) and (III)-mediated free-radical cyclisation of alkenes, β-keto esters and molecular oxygen

  1993cited by this paper
• Homolytic bond dissociation energies of the acidic carbon-hydrogen bonds in .alpha.-substituted and 10-substituted 9-methylanthracenes and their related radical anions

  1993cited by this paper
• Dehydrogenations with lead tetraacetate. Ketone to enone transformations in the 2-(aminocarbonyl)- and 2-(carbalkoxy)cycloalkanone series

  1993cited by this paper
• Kinetic and mechanistic studies of the nonchain radical nucleophilic substitution reactions

  1993cited by this paper
• An Introduction to Free Radicals

  1993cited by this paper
• Some novel concepts in aromatic reactivity

  1993cited by this paper
• Oxidative Generation of Thioalkyl Cations from 2-Tributylstannyl-1,3-dithianes and 1-(Tributylstannyl)alkyl Sulfides and Their Reactions with Olefinic Nucleophiles

  1993cited by this paper
• Formation of carbenes from halo carbon radicals

  1993cited by this paper
• Cobalt(II) catalysed reaction of alkenes with aliphatic aldehydes and molecular oxygen: scope and mechanism

  1993cited by this paper
• trans Ring-fused bicyclic structures by 6-exo-trigonal radical closure: use of the triethylborane–stannane–air system for intramolecular radical addition to aldehydes

  1993cited by this paper
• An AC → ABC approach to taxol involving B-ring closure at C-1–C-2

  1993cited by this paper
• Ligand, solvent, and deuterium isotope effects in Mn(III)-based oxidative free-radical cyclizations

  1993cited by this paper
• SRN1 reactions of aryl halides with carbanions initiated by sodium amalgam in liquid ammonia

  1993cited by this paper
• Reversed Chemoselectivity in Titanium-induced Coupling Reactions: Syntheses of Salvadoricine and Diazepam

  1993cited by this paper
• Anion-Molecule Approaches to Non-Kekulé Molecules: The Radical Anion of Tetramethyleneethane

  1993cited by this paper
• Dehydrogenation of carboxamidoenamines with manganese acetate and copper acetate

  1993cited by this paper
• The Marcus Inverted Region from Theory to Experiment

  1993cited by this paper
• On the SRN1-SRN2 mechanistic possibilities

  1993cited by this paper
• The use of π-organoiron sandwiches in aromatic chemistry

  1993cited by this paper
• A novel one-flask cyclopentannulation involving a dilithiomethane equivalent as a β-connector of two enones. A highly efficient total synthesis of (±)-hirsutene

  1993cited by this paper
• Coupling and disproportionation reactions of alkyl iodides on a single-crystal copper surface : alkyl radicals versus metal alkyls

  1993cited by this paper
• Indirect electroreductive addition of alkyl radicals to activated olefins using a nickel(II) complex as an electron-transfer catalyst

  1993cited by this paper
• Generation of β-Carbonyl Radicals from Cyclopropanol Derivatives by the Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Electron-Rich and -Deficient Olefins

  1993cited by this paper
• Synthesis of functionalized organic molecules containing a tetrafluoroethylene fragment by cobaloxime-promoted fluoroalkylation with substituted tetrafluoroethyl bromides

  1993cited by this paper
• Homolytic aromatic substitutions of pentatomic heteroaromatics with electrophilic carbon radicals generated by alkyl halides and triethylborane

  1993cited by this paper
• Palladium-catalyzed alkylation of allylic nitrates derived from ceric ammonium nitrate promoted oxidative addition of trimethylsilyloxy-cyclopropanes to 1,3-butadiene

  1993cited by this paper
• EPR and spin-trapping investigation of free radicals from the reaction of 4-methoxybenzenediazonium tetrafluoroborate with melanin and melanin precursors

  1993cited by this paper
• Oxidative addition reactions of ?-alkenyl nitronate anions

  1993cited by this paper
• The First Examples of Carbon Monoxide Trapping in a Manganese(III)-Induced Oxidation System

  1993cited by this paper
• Single electron transfer induced elemental steps in the transformation of iodomalonic esters and related CH-acids under solid-liquid PTC conditions. Preparation of electrophilic cyclopropanes

  1993cited by this paper
• Free radical-mediated ring expansion and related annulations

  1993cited by this paper
• Synthesis of non-phenolic bisbenzocyclooctadiene lignan lactones and aporphinic alkaloids, by oxidative coupling with new agents in fluoro acid medium. IV.

  1993cited by this paper
• Kinetic and thermodynamic atropdiastereoselection in the synthesis of the M(5–7) tripeptide portion of vancomycin

  1993cited by this paper
• Mechanism of organocalcium reagent formation

  1993cited by this paper
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(2-pyridinecarboxylate)

  1993cited by this paper
• Radical cation catalyzed pinacol-pinacolone rearrangement

  1993cited by this paper
• Synthesis of either a cis- or trans-fused hydroazulenol from an allylstannane functionalized (E)-5-cyclodecenone

  1993cited by this paper
• Mechanisms of the Ullmann coupling reaction in adsorbed monolayers

  1993cited by this paper
• Cyclization Reactions of α-amino radicals derived from N-(N′,N′-Dialkylaminoalkenyl)benzotriazoles and samarium diiodide

  1993cited by this paper
• Intermolecular reductive cross coupling of carbonyl compounds with nitriles induced by low-valent titanium

  1993cited by this paper
• Mn(III)-Promoted Homolytic Methylmalonylation of Pyrrole and Indole Derivatives. A Simple Route to α-Methyl-2-pyrrole- and α- Methyl-3-indoleacetic Acids.

  1993cited by this paper
• Dynamic Solvent Effects on Electron-Transfer Reactions

  1993cited by this paper
• Radical Cyclization of N-Alkyl-N-Unsaturated Alkyl-ß-Carboxamidoenamines Induced by Manganese Acetate

  1993cited by this paper
• Additive and solvent effects on samarium diiodide reductions: the effects of water and DMPU

  1993cited by this paper

• Hybrid Reaction Systems for the Synthesis of Alkylated Compounds based upon Cu-catalyzed Coupling of Radicals and Organometallic Species.

  2020cites this paper
• Redox-Tag Processes: Intramolecular Electron Transfer and Its Broad Relationship to Redox Reactions in General.

  2017cites this paper
• Oxidation of bis-sulfinyl carbanions as the pivot of ionic/radical tandem reactions

  2016cites this paper
• Oxidative dimerization of 2-chloro-3,3,3-trifluoro- 1-(4-methoxyphenyl)propene in the system PbO2–CF3SO3H

  2016cites this paper
• 15. Dearomatization Reactions

  2015cites this paper
• The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor.

  2014cites this paper
• Solar Synthesis: Prospects in Visible Light Photocatalysis

  2014cites this paper
• Diastereoselective synthesis of fused lactone-pyrrolidinones; application to a formal synthesis of (-)-salinosporamide A.

  2014cites this paper
• 3.11 Pinacol Coupling Reactions

  2014cites this paper
• Facile one-pot method for the synthesis of arylmethanamines

  2014cites this paper
• Visible Light Photocatalysis: The Development of Photocatalytic Radical Ion Cycloadditions.

  2013cites this paper
• Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes

  2013cites this paper
• A once-a-day dosage form for the delivery of insulin through the nasal route: in vitro assessment and in vivo evaluation.

  2013cites this paper
• Organocatalytic Radical and Electron Transfer Reactions

  2013cites this paper
• Manganese(III) Acetate, CAN, and Fe(III) Salts in Oxidative Radical Chemistry

  2012cites this paper
• Electron Transfer Triggers Fast Dimer/Monomer Switching of Pyridinium and Quinolinium Cations

  2012cites this paper
• Accessing the Synthetic Chemistry of Radical Ions

  2012cites this paper
• Transition Metals and Radicals

  2012cites this paper
• Photocatalytic Reductive Cyclizations of Enones: Divergent Reactivity of Photogenerated Radical and Radical Anion Intermediates.

  2011cites this paper
• X-ray photolysis to release ligands from caged reagents by an intramolecular antenna sensitive to magnetic resonance imaging.

  2011cites this paper
• Total synthesis and absolute configuration determination of (+)-subincanadine F.

  2010cites this paper
• Oxidation of alkyl trifluoroborates: an opportunity for tin-free radical chemistry.

  2010cites this paper
• Stereoselective synthesis of bicyclic nitrocyclopropanes by a radical-anion domino reaction.

  2009cites this paper
• Reactions of metal promoted C-C-coupling of coordinated 1,10-phenanthrolines in the synthesis of electron-rich d-element 1,10-phenanthrocyanines

  2009cites this paper
• Highly Selective Synthetic Reactions by the Combined Use of Organometallic Reagents and Radical Species

  2008cites this paper
• Oxidation of aromatic compounds: XVI. Radical cations derived from acetylenic compounds with electron-withdrawing groups: Reactions and ESR parameters

  2008cites this paper
• Cerium(IV)-mediated C–C bond formations in carbohydrate chemistry

  2008cites this paper
• Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides.

  2007cites this paper
• Catalytic Reductive Coupling of Carbonyl Compounds – The Pinacol Coupling Reaction and Beyond

  2007cites this paper
• Tetrahedron reports on organic chemistry

  2007cites this paper
• Generation of Alkene Radical Cations by Heterolysis of β‐Substituted Radicals: Mechanism, Stereochemistry, and Application in Synthesis

  2007cites this paper
• Tricoordinate Carbanions, Cations, and Radicals

  2005cites this paper
• Efficient oxidative radical cyclizations of ester enolates with carbocation desilylation as termination: synthesis of cyclopentanoid monoterpenes and analogues.

  2004cites this paper
• Non‐transition metal‐catalyzed living radical polymerization of vinyl chloride initiated with iodoform in water at 25 °C

  2004cites this paper
• Synthesis of heterocycles by radical cyclisation

  2003cites this paper
• Recent advances in the oxovanadium mediated biaryl coupling and modified Mannich-type reaction

  2003cites this paper
• Tetrahedron reports on organic chemistry: Editors

  2003cites this paper
• Selective reactions of transition-metal-generated radicals

  2002cites this paper
• Efficient MnIII-mediated synthesis of functionalized trans-3,4-disubstituted-γ-butyrolactones

  2002cites this paper
• Addition of malonyl radicals to glycals with C-1 acceptor groups: remarkable influence of the substituents on the product distribution.

  2002cites this paper
• New approaches in radical carbonylation chemistry: fluorous applications and designed tandem processes by species-hybridization with anions and transition metal species.

  2002cites this paper
• Stereoselective reductive radical cyclization of ketonitriles catalyzed by Cp 2 TiCl 2 in the presence of chlorosilane and zinc

  2001cites this paper
• Generation of Radical Species by Single-Electron-Transfer Reactions and Their Application to the Development of Synthetic Reactions

  2001cites this paper
• Radikale in der organischen Synthese

  2000cites this paper
• Mn(OAc)3-promoted hydroxylation of α-carbomethoxy-γ-lactones by molecular oxygen

  2000cites this paper
• Some new aspects in the application of perfluoroalkyl halides in the synthesis of fluorine-containing organic compounds

  2000cites this paper
• Redox reactions via vanadium-induced electron transfer.

  2000cites this paper
• Einfache Synthese vierfach Acceptor‐substituierter Alkene durch formale Dehydrodimerisierung von Malonsäureestern

  2000cites this paper
• Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(pyridine-2-carboxylate) and Its Application to Total Synthesis of 10-Isothiocyanatoguaia-6-ene

  1999cites this paper
• Stereoselective radical-radical coupling reactions of metallated imidazolines

  1999cites this paper
• Iodine transfer cyclization mediated by DIBAL-H/THF

  1999cites this paper
• THE LITERATURE OF HETEROCYCLIC CHEMISTRY, PART VI

  1999cites this paper
• New synthetic methods via radical cation fragmentation

  1998cites this paper
• β- and γ-lactams by nickel powder mediated 4-exo or 5-endo radical cyclisations. A concise construction of the mesembrine skeleton

  1998cites this paper
• Highly selective coupling of organoboron compounds via oxovanadium(V)-induced oxidation

  1998cites this paper
• Electron transfer-induced sequential transformations of malonates by the ferrocenium ion

  1998cites this paper
• Synthesis of bicyclic γ-lactones promoted by Mn(OAc)3: Regio- and diastereoselectivities

  1998cites this paper
• Manganese(III) acetate – A Versatile Reagent for Radical Generation and CC Bond Formation

  1997cites this paper
• OXIDATIVE ADDITION OF DIMETHYL MALONATE TO STYRENES MEDIATED BY CERIUM(IV)AMMONIUM NITRATE : SOME NOVEL OBSERVATIONS

  1997cites this paper
• Novel Cerium(IV) ammonium nitrate induced dimerization of methoxystyrenes

  1997cites this paper
• Tandem annulations: a one operation construction of bicyclo[3.3.0]octan-1-ol and bicyclo[3.2.1]octan-1-ol skeletons by a three-component coupling reaction of alk-4-enyl iodides with CO and alkenes in the presence of zinc

  1997cites this paper
• Transition metals in organic synthesis. Highlights for the year 1995

  1997cites this paper
• Carbon–carbon bond forming reactions mediated by cerium(IV) reagents

  1997cites this paper
• Halogen atom transfer radical cyclization of N-allyl-N-benzyl-2,2-dihaloamides to 2-pyrrolidinones, promoted by Fe0-FeCl3 or CuCl-TMEDA

  1997cites this paper
• UBERGANGSMETALL-INDUZIERTE RADIKALREAKTIONEN ALS EINFACHER ZUGANG ZU 2-C-ANALOGA VON KOHLENHYDRATEN

  1996cites this paper
• Fe0 initiated halogen atom transfer radical addition of methyl 2-Br-2-Cl-carboxylates to olefins

  1996cites this paper
• Oxidative Addition of 4-Hydroxycoumarin to Alkenes. An Expeditious Entry to 2,3-Dihydro-4H-furo-[3,2-c][1]benzopyran-4-ones1

  1996cites this paper
• Chapter 2 Radical methods in the synthesis of heterocyclic compounds

  1996cites this paper
• Novel and practical preparation of α-fluoro-functionalized esters from fluoroiodoacetates

  1996cites this paper
• Redox Induced Radical and Radical Ionic Carbon‐Carbon Bond Forming Reactions

  1995cites this paper