Synthesis, stability, and structure of gadolinium(III) and yttrium(III) macrocyclic poly(amino carboxylates)

No abstract is available for this paper.

• Publication year

  1994

• Venue

  Inorganic Chemistry

• Publication date

  1994-08-03

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1021/IC00094A021
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• Stereochemistry of rare earth polyaminocarboxylate complexes

  2026cites this paper
• Current Status and Advancements in Radiotheranostics and Targeted Radionuclide Therapy in Malaysia

  2025cites this paper
• Digadoglucitol: A New High Relaxivity MRI Contrast Agent Based on the Dimerization of [Gd(HP-DO3A)] and Activated Intramolecular Catalysis of the Prototropic Exchange

  2025cites this paper
• Precipitation of gadolinium from magnetic resonance imaging contrast agents may be the Brass tacks of toxicity.

  2025cites this paper
• Exploring the potential of a bioassembler for protein crystallization in space

  2025cites this paper
• Synthesis of an Ethylenediaminetetraacetic Acid-like Ligand Based on Sucrose Scaffold and Complexation and Proton Relaxivity Studies of Its Gadolinium(III) Complex in Solution

  2024cites this paper
• Insights into Molecular Lanthanide Complexes: Construction, Properties and Bioimaging and Biosensing Applications

  2024cites this paper
• Coordinative diversity of lanthanum(III), praseodymium(III), yttrium(III) and zinc(II) complexes based cyclen-tetraphenolate

  2023cites this paper
• PVA-Microbubbles as a Radioembolization Platform: Formulation and the In Vitro Proof of Concept

  2023cites this paper
• Cyclen-based artificial nucleases: Three decades of development (1989–2022). Part a – Hydrolysis of phosphate esters

  2023cites this paper
• An Electrolyte-Gated Graphene Field-Effect Transistor for Detection of Gadolinium(III) in Aqueous Media

  2023cites this paper
• N,N-Alkylation Clarifies the Role of N- and O-Protonated Intermediates in Cyclen-Based 64Cu Radiopharmaceuticals.

  2022cites this paper
• Versatile Macrocyclic Platform for the Complexation of [natY/90Y]Yttrium and Lanthanide Ions

  2022cites this paper
• Highly efficient potentiometric sensing device for gadolinium based on Tetraazacyclododecane-1, 4, 7, 10 -tetraaceticacid crown ether and multiwalled carbon nanotube composite

  2022cites this paper
• Stability Estimation of Gallium Complexes of DOTA Derivatives for Radiotheranostic Applications

  2022cites this paper
• Exploring Cyclic Aminopolycarboxylate Ligands for Sb(III) Complexation: PCTA and Its Derivatives as a Promising Solution.

  2021cites this paper
• Aminopolycarboxylates in trivalent f-element separations

  2021cites this paper
• How the Chemical Properties of GBCAs Influence Their Safety Profiles In Vivo

  2021cites this paper
• How the catalysis of the prototropic exchange affects the properties of lanthanide(III) complexes in their applications as MRI contrast agents

  2021cites this paper
• H-Bonding and intramolecular catalysis of proton exchange affect the CEST properties of EuIII complexes with HP-DO3A-like ligands.

  2021cites this paper
• Complexes of Bifunctional DO3A-N-(α-amino)propinate Ligands with Mg(II), Ca(II), Cu(II), Zn(II), and Lanthanide(III) Ions: Thermodynamic Stability, Formation and Dissociation Kinetics, and Solution Dynamic NMR Studies

  2021cites this paper
• An albumin-binding Gd-HPDO3A contrast agent for improved intravascular retention

  2021cites this paper
• Underlining the Importance of Peripheral Protic Functional Groups to Enhance the Proton Exchange of Gd-Based MRI Contrast Agents

  2021cites this paper
• Enhanced relaxivity of GdIII-complexes with HP-DO3A-like ligands upon the activation of the intramolecular catalysis of the prototropic exchange

  2021cites this paper
• Acid-catalyzed proton exchange as a novel approach for relaxivity enhancement in Gd-HPDO3A-like complexes†

  2020cites this paper
• The Use of the Macrocyclic Chelator DOTA in Radiochemical Separations

  2020cites this paper
• Macrocyclic MR contrast agents: evaluation of multiple-organ gadolinium retention in healthy rats

  2020cites this paper
• Albumin-based nanoparticles as contrast medium for MRI: vascular imaging, tissue and cell interactions, and pharmacokinetics of second-generation nanoparticles

  2020cites this paper
• The use of yttrium in medical imaging and therapy: historical background and future perspectives.

  2020cites this paper
• Albumin-based nanoparticles as contrast medium for MRI: vascular imaging, tissue and cell interactions, and pharmacokinetics of second-generation nanoparticles

  2020cites this paper
• Lipid-nanodiscs formed by paramagnetic metal chelated polymer for fast NMR data acquisition.

  2020cites this paper
• Toward novel sulphur-containing derivatives of tetraazacyclododecane: synthesis, acid–base properties, spectroscopic characterization, DFT calculations, and cadmium(ii) complex formation in aqueous solution

  2020cites this paper
• Unexpected Trends in the Stability and Dissociation Kinetics of Lanthanide(III) Complexes with Cyclen-Based Ligands across the Lanthanide Series.

  2020cites this paper
• Dy-DTPA as supersensitive shifting and relaxational probe for NMR/MRI control of local temperature

  2020cites this paper
• Towards an improved design of MRI Contrast Agents: Synthesis and Relaxometric Characterisation of Gd-HPDO3A Analogues.

  2020cites this paper
• Yttrium-86 is a Positron Emitting Surrogate of Gadolinium for Noninvasive Quantification of Whole-Body Distribution of Gadolinium-Based Contrast Agents.

  2019cites this paper
• Covalency and magnetic anisotropy in lanthanide single molecule magnets: the DyDOTA archetype

  2019cites this paper
• Ligand design strategies to increase stability of gadolinium-based magnetic resonance imaging contrast agents

  2019cites this paper
• Design of gadoteridol-loaded cationic liposomal adjuvant CAF01 for MRI of lung deposition of intrapulmonary administered particles.

  2019cites this paper
• A new series of lanthanide complexes with the trans-disubstituted Py2[18]aneN6 macrocyclic ligand: synthesis, structures and properties

  2019cites this paper
• The biological fate of gadolinium-based MRI contrast agents: a call to action for bioinorganic chemists.

  2019cites this paper
• Coordination Behavior of 1,4-Disubstituted Cyclen Endowed with Phosphonate, Phosphonate Monoethylester, and H-Phosphinate Pendant Arms

  2019cites this paper
• Exploring the intramolecular catalysis of the proton exchange process to modulate the relaxivity of Gd(iii)-complexes of HP-DO3A-like ligands.

  2018cites this paper
• Synthesis and Unprecedented Complexation Properties of β-Cyclodextrin-Based Ligand for Lanthanide Ions.

  2018cites this paper
• Dinuclear Lanthanide(III)-m-ODO2A-dimer Macrocyclic Complexes: Solution Speciation, DFT Calculations, Luminescence Properties, and Promoted Nitrophenyl-Phosphate Hydrolysis Rates.

  2018cites this paper
• Small-Molecule Lanthanide Complexes Probe for Second Near-Infrared Window Bioimaging.

  2018cites this paper
• Radioactive Main Group and Rare Earth Metals for Imaging and Therapy.

  2018cites this paper
• Structural and Spectral (IR, NMR and UV/Visible) Properties of Newly Designed Boronic Acid Derivatives Containing DO3A Sensitive to Uranyl Ion: A DFT and TD-DFT Study

  2017cites this paper
• Lanthanide Macrocyclic Complexes: Structure, Thermodynamics, Kinetics, and Applications

  2017cites this paper
• Structural and Spectral ( IR , NMR and UV / Visible ) Properties of Newly Designed Boronic Acid Derivatives Containing DO 3 A Sensitive to Uranyl Ion : A DFT and TD-DFT Study

  2017cites this paper
• A Perspective on Lanthanide Chemistry

  2016cites this paper
• A simple approach to a new T8-POSS based MRI contrast agent.

  2016cites this paper
• Cyclen-based Gd3+ complexes as MRI contrast agents: Relaxivity enhancement and ligand design.

  2016cites this paper
• MRI CEST at 1T with large µeff Ln3+ complexes T m3+‐HPDO3A: An efficient MRI pH reporter

  2016cites this paper
• Pyclen Tri-n-butylphosphonate Ester as Potential Chelator for Targeted Radiotherapy: From Yttrium(III) Complexation to (90)Y Radiolabeling.

  2016cites this paper
• pH-Responsive Relaxometric Behaviour of Coordination Polymer Nanoparticles Made of a Stable Macrocyclic Gadolinium Chelate.

  2016cites this paper
• Basic MR relaxation mechanisms and contrast agent design

  2015cites this paper
• A shortcut to high-affinity Ga-68 and Cu-64 radiopharmaceuticals: one-pot click chemistry trimerisation on the TRAP platform.

  2015cites this paper
• Gd(3+)-Based Magnetic Resonance Imaging Contrast Agent Responsive to Zn(2+).

  2015cites this paper
• Optimized co-solute paramagnetic relaxation enhancement for the rapid NMR analysis of a highly fibrillogenic peptide

  2015influential citation
• Synthesis and Structural Analysis of 1,4,7,10-Tetraazacyclododecane-1,4,7,10-­tetraazidoethylacetic Acid (DOTAZA) Complexes

  2015cites this paper
• Optimization Strategies for ParaCEST Contrast Agents in MRI

  2015cites this paper
• Thermodynamic stability, kinetic inertness and relaxometric properties of monoamide derivatives of lanthanide(III) DOTA complexes.

  2015cites this paper
• Molecular Platform for Design and Synthesis of Targeted Dual-Modality Imaging Probes

  2015cites this paper
• Developing New Ligand Platforms for MRI Contrast Agents

  2014cites this paper
• Substitution of gadolinium ethylenediaminetetraacetate with phosphites: towards gadolinium deposit in nephrogenic systemic fibrosis.

  2014cites this paper
• Matching chelators to radiometals for radiopharmaceuticals.

  2014cites this paper
• Underscoring the influence of inorganic chemistry on nuclear imaging with radiometals.

  2014cites this paper
• Paramagnetic doping of a 7TM membrane protein in lipid bilayers by Gd3+-complexes for solid-state NMR spectroscopy

  2014influential citation
• Bifunctional Chelates Optimized for Molecular MRI

  2014cites this paper
• The issues and tentative solutions for contrast-enhanced magnetic resonance imaging at ultra-high field strength.

  2014cites this paper
• A complement to the modern crystallographer's toolbox: caged gadolinium complexes with versatile binding modes.

  2014influential citation
• Peptide optimization and conjugation strategies in the development of molecularly targeted magnetic resonance imaging contrast agents.

  2014cites this paper
• The Chemistry of Lanthanide MRI Contrast Agents

  2014cites this paper
• An enzymatic approach to bifunctional chelating agents.

  2014cites this paper
• Solution structures, stabilities, kinetics, and dynamics of DO3A and DO3A-sulphonamide complexes.

  2014cites this paper
• A QUANTUM MECHANICAL STUDY OF STRUCTURAL AND ELECTRONIC DILUTION EFFECTS IN PARAMAGNETIC CHEMICAL EXCHANGE SATURATION TRANSFER AGENTS.

  2014cites this paper
• Lanthanide Complexes with Heteroditopic Ligands as Fluorescent Zinc Sensors

  2014cites this paper
• A rapid, automated gradient flow injection-spectrophotometric technique for study of metal complexation reactions.

  2014cites this paper
• Phosphinic Acid Functionalized Polyazacycloalkane Chelators for Radiodiagnostics and Radiotherapeutics: Unique Characteristics and Applications

  2014cites this paper
• Modular syntheses of H₄octapa and H₂dedpa, and yttrium coordination chemistry relevant to ⁸⁶Y/⁹⁰Y radiopharmaceuticals.

  2014cites this paper
• Stability and Toxicity of Contrast Agents

  2013cites this paper
• Metal-Based MRI Contrast Agents

  2013cites this paper
• Lanthanide(III) chelates as MRI contrast agents: A brief description

  2013cites this paper
• Lanthanide(III) complexes of aminoethyl-DO3A as PARACEST contrast agents based on decoordination of the weakly bound amino group.

  2013cites this paper
• Design of Porphyrin-dota-Like Scaffolds as All-in-One Multimodal Heterometallic Complexes for Medical Imaging

  2013cites this paper
• Multifunctional magnetic and fluorescent nanoparticles for beta-amyloid targeting in neurodegenerative disease diagnosis

  2013cites this paper
• Structure, Dynamics, and Computational Studies of Lanthanide‐Based Contrast Agents

  2013cites this paper
• [Gd(CyPic3A)(H2O)2]-: a stable, bis(aquated) and high-relaxivity Gd(III) complex.

  2013cites this paper
• Hyperfine interactions in a gadolinium-based MRI contrast agent: high-frequency modulations from ab initio simulations.

  2013cites this paper
• The ubiquitous DOTA and its derivatives: the impact of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid on biomedical imaging.

  2013cites this paper
• Combined high resolution NMR and 1H and 17O relaxometric study sheds light on the solution structure and dynamics of the lanthanide(III) complexes of HPDO3A.

  2013cites this paper
• Synthesis and characterization of a hypoxia-sensitive MRI probe.

  2012cites this paper
• Identification and quantification of potential metabolites of Gd-based contrast agents by electrochemistry/separations/mass spectrometry.

  2012cites this paper
• Di-nuclear nonionic magnetic resonance contrast agents using pyrazinyl linking centers

  2012cites this paper
• Fluorescent aza-cyclophanes derived from diethylenetriaminepentaacetic acid (DTPA), and their complexation with Gd(III)

  2012cites this paper
• The Development of Iron(II) Complexes as ParaCEST MRI Contrast Agents

  2012cites this paper
• The Solution Structure and Dynamics of MRI Probes Based on Lanthanide(III) DOTA as Investigated by DFT and NMR Spectroscopy

  2012cites this paper
• Hydroxypyridinones as “privileged” chelating structures for the design of medicinal drugs

  2012cites this paper
• Synthesis and characterization of a paramagnetic sialic acid conjugate as probe for magnetic resonance applications.

  2012cites this paper