Photoinduced Deaminative Borylation of Alkylamines.

An operationally simple deaminative borylation reaction of primary alkylamines has been developed. The formation of electron-donor-acceptor complexes between N-alkylpyridinium salts and bis(catecholato)diboron enables photoinduced single-electron transfer and fragmentation to carbon-centered radicals, which are subsequently borylated. The mild conditions allow a diverse range of readily available alkylamines to be efficiently converted into synthetically valuable alkylboronic esters under catalyst-free conditions.

• Publication year

  2018

• Venue

  Journal of the American Chemical Society

• Publication date

  2018-08-09

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/jacs.8b07103PMID 30091912
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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